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Early Main Group Metal Catalysts for Imine Hydrosilylation
The efficient catalytic reduction of imines with phenylsilane is achieved by using the potassium, calcium and strontium based catalysts [(DMAT)K (THF)](∞), (DMAT)(2)Ca⋅(THF)(2) and (DMAT)(2)Sr⋅(THF)(2) (DMAT=2‐dimethylamino‐α‐trimethylsilylbenzyl). Eight different aldimines and the ketimine Ph(2)C=N...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973166/ https://www.ncbi.nlm.nih.gov/pubmed/31617621 http://dx.doi.org/10.1002/chem.201904148 |