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Early Main Group Metal Catalysts for Imine Hydrosilylation

The efficient catalytic reduction of imines with phenylsilane is achieved by using the potassium, calcium and strontium based catalysts [(DMAT)K (THF)](∞), (DMAT)(2)Ca⋅(THF)(2) and (DMAT)(2)Sr⋅(THF)(2) (DMAT=2‐dimethylamino‐α‐trimethylsilylbenzyl). Eight different aldimines and the ketimine Ph(2)C=N...

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Detalles Bibliográficos
Autores principales: Elsen, Holger, Fischer, Christian, Knüpfer, Christian, Escalona, Ana, Harder, Sjoerd
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973166/
https://www.ncbi.nlm.nih.gov/pubmed/31617621
http://dx.doi.org/10.1002/chem.201904148