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Manganese(I)‐Catalyzed β‐Methylation of Alcohols Using Methanol as C(1) Source
Highly selective β‐methylation of alcohols was achieved using an earth‐abundant first row transition metal in the air stable molecular manganese complex [Mn(CO)(2)Br[HN(C(2)H(4)P(i)Pr(2))(2)]] 1 ([HN(C(2)H(4)P(i)Pr(2))(2)]=MACHO‐(i)Pr). The reaction requires only low loadings of 1 (0.5 mol %), metha...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973237/ https://www.ncbi.nlm.nih.gov/pubmed/31651071 http://dx.doi.org/10.1002/anie.201909035 |