A Systematic Survey of the Reactivity of Chlorinated N(2)P(2), NP(3) and P(4) Ring Systems

The reactivity of the four‐membered NP(3) ring system [RN(μ‐PCl)(2)PR] (R=Mes*=2,4,6‐tri‐tert‐butylphenyl) towards Lewis acids, Lewis bases, and reducing agents was investigated. Comparisons with the literature‐known, analogous cyclic compounds [ClP(μ‐NR)](2) (R=Ter=2,6‐dimesitylphenyl) and [ClP(μ‐P...

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Autores principales: Bresien, Jonas, Eickhoff, Liesa, Schulz, Axel, Suhrbier, Tim, Villinger, Alexander
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973262/
https://www.ncbi.nlm.nih.gov/pubmed/31589354
http://dx.doi.org/10.1002/chem.201903410
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author Bresien, Jonas
Eickhoff, Liesa
Schulz, Axel
Suhrbier, Tim
Villinger, Alexander
author_facet Bresien, Jonas
Eickhoff, Liesa
Schulz, Axel
Suhrbier, Tim
Villinger, Alexander
author_sort Bresien, Jonas
collection PubMed
description The reactivity of the four‐membered NP(3) ring system [RN(μ‐PCl)(2)PR] (R=Mes*=2,4,6‐tri‐tert‐butylphenyl) towards Lewis acids, Lewis bases, and reducing agents was investigated. Comparisons with the literature‐known, analogous cyclic compounds [ClP(μ‐NR)](2) (R=Ter=2,6‐dimesitylphenyl) and [ClP(μ‐PR)](2) (R=Mes*) are drawn, to obtain a better systematic understanding of the reactivity of cyclic NP species. Apart from experimental results, DFT computations are discussed to further the insight into bonding and electronic structure of these compounds.
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spelling pubmed-69732622020-01-27 A Systematic Survey of the Reactivity of Chlorinated N(2)P(2), NP(3) and P(4) Ring Systems Bresien, Jonas Eickhoff, Liesa Schulz, Axel Suhrbier, Tim Villinger, Alexander Chemistry Full Papers The reactivity of the four‐membered NP(3) ring system [RN(μ‐PCl)(2)PR] (R=Mes*=2,4,6‐tri‐tert‐butylphenyl) towards Lewis acids, Lewis bases, and reducing agents was investigated. Comparisons with the literature‐known, analogous cyclic compounds [ClP(μ‐NR)](2) (R=Ter=2,6‐dimesitylphenyl) and [ClP(μ‐PR)](2) (R=Mes*) are drawn, to obtain a better systematic understanding of the reactivity of cyclic NP species. Apart from experimental results, DFT computations are discussed to further the insight into bonding and electronic structure of these compounds. John Wiley and Sons Inc. 2019-11-22 2019-12-18 /pmc/articles/PMC6973262/ /pubmed/31589354 http://dx.doi.org/10.1002/chem.201903410 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Full Papers
Bresien, Jonas
Eickhoff, Liesa
Schulz, Axel
Suhrbier, Tim
Villinger, Alexander
A Systematic Survey of the Reactivity of Chlorinated N(2)P(2), NP(3) and P(4) Ring Systems
title A Systematic Survey of the Reactivity of Chlorinated N(2)P(2), NP(3) and P(4) Ring Systems
title_full A Systematic Survey of the Reactivity of Chlorinated N(2)P(2), NP(3) and P(4) Ring Systems
title_fullStr A Systematic Survey of the Reactivity of Chlorinated N(2)P(2), NP(3) and P(4) Ring Systems
title_full_unstemmed A Systematic Survey of the Reactivity of Chlorinated N(2)P(2), NP(3) and P(4) Ring Systems
title_short A Systematic Survey of the Reactivity of Chlorinated N(2)P(2), NP(3) and P(4) Ring Systems
title_sort systematic survey of the reactivity of chlorinated n(2)p(2), np(3) and p(4) ring systems
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973262/
https://www.ncbi.nlm.nih.gov/pubmed/31589354
http://dx.doi.org/10.1002/chem.201903410
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