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Generation of Organozinc Reagents by Nickel Diazadiene Complex Catalyzed Zinc Insertion into Aryl Sulfonates

The generation of arylzinc reagents (ArZnX) by direct insertion of zinc into the C−X bond of ArX electrophiles has typically been restricted to iodides and bromides. The insertions of zinc dust into the C−O bonds of various aryl sulfonates (tosylates, mesylates, triflates, sulfamates), or into the C...

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Detalles Bibliográficos
Autores principales: Klein, Philippe, Lechner, Vivien Denise, Schimmel, Tanja, Hintermann, Lukas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973264/
https://www.ncbi.nlm.nih.gov/pubmed/31591766
http://dx.doi.org/10.1002/chem.201904545