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Dimensional Stable Lead Electrode Modified by SDS for Efficient Degradation of Bisphenol A

[Image: see text] The dimensional stable lead electrodes modified by sodium dodecyl sulfate (SDS) were prepared with electrochemical deposition and it shows that a more compact, uniform, and smooth film of Ti/PbO(2)(F+SDS) electrode reduces the corroded crystal faces and surface defects. Characteriz...

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Autores principales: Chen, Danni, Xiong, Fengqing, Zhang, Hao, Ma, Chenglong, Cao, Limei, Yang, Ji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6977255/
https://www.ncbi.nlm.nih.gov/pubmed/31984277
http://dx.doi.org/10.1021/acsomega.9b03571
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author Chen, Danni
Xiong, Fengqing
Zhang, Hao
Ma, Chenglong
Cao, Limei
Yang, Ji
author_facet Chen, Danni
Xiong, Fengqing
Zhang, Hao
Ma, Chenglong
Cao, Limei
Yang, Ji
author_sort Chen, Danni
collection PubMed
description [Image: see text] The dimensional stable lead electrodes modified by sodium dodecyl sulfate (SDS) were prepared with electrochemical deposition and it shows that a more compact, uniform, and smooth film of Ti/PbO(2)(F+SDS) electrode reduces the corroded crystal faces and surface defects. Characterization results demonstrate that the oxygen evolution potential (OEP) of the Ti/PbO(2)(F+SDS) electrode was higher, and its service life is almost 1.6 times longer than the Ti/PbO(2)(F) electrode. Compared with Ti/PbO(2)(F) electrode, the soluble Pb concentration of the Ti/PbO(2)(F+SDS) electrode decreased 15.1%, which indicates that the decrease of crystal surface defects leads to the reduction of Pb ions so that the excellent corrosion resistance electrodes cause low environmental risks. The modified electrodes were used as anodes to degrading bisphenol A (BPA) when an electrolyte is 0.2 M Na(2)SO(4), the applied voltage is 5 V and electrodes distance is 3 cm, 20 mg/L BPA for electrolysis time of 180 min can reach up to 97.6%.
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spelling pubmed-69772552020-01-24 Dimensional Stable Lead Electrode Modified by SDS for Efficient Degradation of Bisphenol A Chen, Danni Xiong, Fengqing Zhang, Hao Ma, Chenglong Cao, Limei Yang, Ji ACS Omega [Image: see text] The dimensional stable lead electrodes modified by sodium dodecyl sulfate (SDS) were prepared with electrochemical deposition and it shows that a more compact, uniform, and smooth film of Ti/PbO(2)(F+SDS) electrode reduces the corroded crystal faces and surface defects. Characterization results demonstrate that the oxygen evolution potential (OEP) of the Ti/PbO(2)(F+SDS) electrode was higher, and its service life is almost 1.6 times longer than the Ti/PbO(2)(F) electrode. Compared with Ti/PbO(2)(F) electrode, the soluble Pb concentration of the Ti/PbO(2)(F+SDS) electrode decreased 15.1%, which indicates that the decrease of crystal surface defects leads to the reduction of Pb ions so that the excellent corrosion resistance electrodes cause low environmental risks. The modified electrodes were used as anodes to degrading bisphenol A (BPA) when an electrolyte is 0.2 M Na(2)SO(4), the applied voltage is 5 V and electrodes distance is 3 cm, 20 mg/L BPA for electrolysis time of 180 min can reach up to 97.6%. American Chemical Society 2020-01-07 /pmc/articles/PMC6977255/ /pubmed/31984277 http://dx.doi.org/10.1021/acsomega.9b03571 Text en Copyright © 2020 American Chemical Society This is an open access article published under an ACS AuthorChoice License (http://pubs.acs.org/page/policy/authorchoice_termsofuse.html) , which permits copying and redistribution of the article or any adaptations for non-commercial purposes.
spellingShingle Chen, Danni
Xiong, Fengqing
Zhang, Hao
Ma, Chenglong
Cao, Limei
Yang, Ji
Dimensional Stable Lead Electrode Modified by SDS for Efficient Degradation of Bisphenol A
title Dimensional Stable Lead Electrode Modified by SDS for Efficient Degradation of Bisphenol A
title_full Dimensional Stable Lead Electrode Modified by SDS for Efficient Degradation of Bisphenol A
title_fullStr Dimensional Stable Lead Electrode Modified by SDS for Efficient Degradation of Bisphenol A
title_full_unstemmed Dimensional Stable Lead Electrode Modified by SDS for Efficient Degradation of Bisphenol A
title_short Dimensional Stable Lead Electrode Modified by SDS for Efficient Degradation of Bisphenol A
title_sort dimensional stable lead electrode modified by sds for efficient degradation of bisphenol a
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6977255/
https://www.ncbi.nlm.nih.gov/pubmed/31984277
http://dx.doi.org/10.1021/acsomega.9b03571
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