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Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift

Reactions that efficiently construct medium-sized lactones are significant, as they overcome the unfavorable entropic factor and transannular interactions for ring closure, and the lactones produced are common structural motifs recurring in many biologically active compounds. Herein, we describe a v...

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Detalles Bibliográficos
Autores principales: Yu, Yinghua, Chakraborty, Pushkin, Song, Jinshuai, Zhu, Lei, Li, Chunsen, Huang, Xueliang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6978448/
https://www.ncbi.nlm.nih.gov/pubmed/31974346
http://dx.doi.org/10.1038/s41467-019-14101-5