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Palladium(0)/benzoic acid catalysis merges sequences with D(2)O-promoted labelling of C–H bonds

The combination of a Pd(0) complex with benzoic acid in the presence of D(2)O enables the synthesis of valuable families of highly deuterated organics through elaborate sequential reactions. The catalytic system can convert 2-butyne fragments into the corresponding d-dienamides, which can then readi...

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Detalles Bibliográficos
Autores principales: Cera, Gianpiero, Della Ca', Nicola, Maestri, Giovanni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6979390/
https://www.ncbi.nlm.nih.gov/pubmed/32110316
http://dx.doi.org/10.1039/c9sc03682b