Deoxygenative trifluoromethylthiolation of carboxylic acids

Here we describe a deoxygenative trifluoromethylthiolation method that yields trifluoromethyl thioesters from readily available carboxylic acids. The method is built upon an “umpolung” strategy where triphenylphosphine is used to first activate an electrophilic trifluoromethylthiolating reagent and...

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Detalles Bibliográficos
Autores principales: Mao, Runze, Bera, Srikrishna, Cheseaux, Alexis, Hu, Xile
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6979494/
https://www.ncbi.nlm.nih.gov/pubmed/32055327
http://dx.doi.org/10.1039/c9sc03396c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6979494/
https://www.ncbi.nlm.nih.gov/pubmed/32055327
http://dx.doi.org/10.1039/c9sc03396c

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