Phase Formation Behavior and Thermoelectric Transport Properties of P-Type Yb(x)Fe(3)CoSb(12) Prepared by Melt Spinning and Spark Plasma Sintering

Formation of multiple phases is considered an effective approach for enhancing the performance of thermoelectric materials since it can reduce the thermal conductivity and improve the power factor. Herein, we report the in-situ generation of a submicron-scale (~500 nm) heterograin structure in p-type Yb-filled (Fe,Co)(4)Sb(12) skutterudites during the melt spinning process. Mixed grains of Yb(x)Fe(3−y)Co(1+y)Sb(12) and Yb(z)Fe(3+y)Co(1−y)Sb(12) were formed in melt spun ribbons due to uneven distribution of cations. By the formation of interfaces between two different grains, the power factor was enhanced due to the formation of an energy barrier for carrier transport, and simultaneously the lattice thermal conductivity was reduced due to the intensified boundary phonon scattering. A high thermoelectric figure of merit zT of 0.66 was obtained at 700 K.