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Synthesis and Dissolution of Metal Oxides in Ionic Liquids and Deep Eutectic Solvents
Ionic liquids (ILs) and deep eutectic solvents (DESs) have proven to be suitable solvents and reactants for low-temperature reactions. To date, several attempts were made to apply this promising class of materials to metal oxide chemistry, which, conventionally, is performed at high temperatures. Th...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6983208/ https://www.ncbi.nlm.nih.gov/pubmed/31878305 http://dx.doi.org/10.3390/molecules25010078 |
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author | Richter, Janine Ruck, Michael |
author_facet | Richter, Janine Ruck, Michael |
author_sort | Richter, Janine |
collection | PubMed |
description | Ionic liquids (ILs) and deep eutectic solvents (DESs) have proven to be suitable solvents and reactants for low-temperature reactions. To date, several attempts were made to apply this promising class of materials to metal oxide chemistry, which, conventionally, is performed at high temperatures. This review gives an overview about the scientific approaches of the synthesis as well as the dissolution of metal oxides in ILs and DESs. A wide range of metal oxides along with numerous ILs and DESs are covered by this research. With ILs and DESs being involved, many metal oxide phases as well as different particle morphologies were obtained by means of relatively simple reactions paths. By the development of acidic task-specific ILs and DESs, even difficultly soluble metal oxides were dissolved and, hence, made accessible for downstream chemistry. Especially the role of ILs in these reactions is in the focus of discussion. |
format | Online Article Text |
id | pubmed-6983208 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-69832082020-02-06 Synthesis and Dissolution of Metal Oxides in Ionic Liquids and Deep Eutectic Solvents Richter, Janine Ruck, Michael Molecules Review Ionic liquids (ILs) and deep eutectic solvents (DESs) have proven to be suitable solvents and reactants for low-temperature reactions. To date, several attempts were made to apply this promising class of materials to metal oxide chemistry, which, conventionally, is performed at high temperatures. This review gives an overview about the scientific approaches of the synthesis as well as the dissolution of metal oxides in ILs and DESs. A wide range of metal oxides along with numerous ILs and DESs are covered by this research. With ILs and DESs being involved, many metal oxide phases as well as different particle morphologies were obtained by means of relatively simple reactions paths. By the development of acidic task-specific ILs and DESs, even difficultly soluble metal oxides were dissolved and, hence, made accessible for downstream chemistry. Especially the role of ILs in these reactions is in the focus of discussion. MDPI 2019-12-24 /pmc/articles/PMC6983208/ /pubmed/31878305 http://dx.doi.org/10.3390/molecules25010078 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Review Richter, Janine Ruck, Michael Synthesis and Dissolution of Metal Oxides in Ionic Liquids and Deep Eutectic Solvents |
title | Synthesis and Dissolution of Metal Oxides in Ionic Liquids and Deep Eutectic Solvents |
title_full | Synthesis and Dissolution of Metal Oxides in Ionic Liquids and Deep Eutectic Solvents |
title_fullStr | Synthesis and Dissolution of Metal Oxides in Ionic Liquids and Deep Eutectic Solvents |
title_full_unstemmed | Synthesis and Dissolution of Metal Oxides in Ionic Liquids and Deep Eutectic Solvents |
title_short | Synthesis and Dissolution of Metal Oxides in Ionic Liquids and Deep Eutectic Solvents |
title_sort | synthesis and dissolution of metal oxides in ionic liquids and deep eutectic solvents |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6983208/ https://www.ncbi.nlm.nih.gov/pubmed/31878305 http://dx.doi.org/10.3390/molecules25010078 |
work_keys_str_mv | AT richterjanine synthesisanddissolutionofmetaloxidesinionicliquidsanddeepeutecticsolvents AT ruckmichael synthesisanddissolutionofmetaloxidesinionicliquidsanddeepeutecticsolvents |