A novel Pt(iv) mono azido mono triazolato complex evolves azidyl radicals following irradiation with visible light

The platinum(iv) azido complex trans,trans,trans-[Pt(IV)(N(3))(2)(OH)(2)(py)(2)] (1) undergoes cycloaddition with 1,4-diphenyl-2-butyne-1,4-dione (2) under mild, catalyst-free conditions, affording a number of mono and bis click products. The major mono click product (3) exists in MeCN as an equilib...

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Detalles Bibliográficos
Autores principales: Yao, Kezi, Bertran, Arnau, Morgan, Jacques, Hare, Samuel M., Rees, Nicholas H., Kenwright, Alan M., Edkins, Katharina, Bowen, Alice M., Farrer, Nicola J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6984332/
https://www.ncbi.nlm.nih.gov/pubmed/31012460
http://dx.doi.org/10.1039/c9dt01156k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6984332/
https://www.ncbi.nlm.nih.gov/pubmed/31012460
http://dx.doi.org/10.1039/c9dt01156k

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