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A novel Pt(iv) mono azido mono triazolato complex evolves azidyl radicals following irradiation with visible light
The platinum(iv) azido complex trans,trans,trans-[Pt(IV)(N(3))(2)(OH)(2)(py)(2)] (1) undergoes cycloaddition with 1,4-diphenyl-2-butyne-1,4-dione (2) under mild, catalyst-free conditions, affording a number of mono and bis click products. The major mono click product (3) exists in MeCN as an equilib...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6984332/ https://www.ncbi.nlm.nih.gov/pubmed/31012460 http://dx.doi.org/10.1039/c9dt01156k |