Cargando…

Proficiency test on the determination of polyethylene and polybutylene terephthalate cyclic oligomers in a food simulant

The outcome of a proficiency test (PT) organised by the European Union Reference Laboratory for Food Contact Materials (EURL-FCM) is presented. The PT was set up to assess the analytical performance of National Reference Laboratories (NRLs) and Official Control Laboratories (OCLs) in the determinati...

Descripción completa

Detalles Bibliográficos
Autores principales: Tsochatzis, Emmanouil D., Alberto Lopes, Joao, Dehouck, Pieter, Robouch, Piotr, Hoekstra, Eddo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6988440/
https://www.ncbi.nlm.nih.gov/pubmed/32128312
http://dx.doi.org/10.1016/j.fpsl.2019.100441
_version_ 1783492262991233024
author Tsochatzis, Emmanouil D.
Alberto Lopes, Joao
Dehouck, Pieter
Robouch, Piotr
Hoekstra, Eddo
author_facet Tsochatzis, Emmanouil D.
Alberto Lopes, Joao
Dehouck, Pieter
Robouch, Piotr
Hoekstra, Eddo
author_sort Tsochatzis, Emmanouil D.
collection PubMed
description The outcome of a proficiency test (PT) organised by the European Union Reference Laboratory for Food Contact Materials (EURL-FCM) is presented. The PT was set up to assess the analytical performance of National Reference Laboratories (NRLs) and Official Control Laboratories (OCLs) in the determination of mass fractions of polyethylene terephthalate (PET) and polybutylene terephthalate (PBT) cyclic dimers and trimers in the official food simulant D1 containing ethanol and water (50:50 v/v). The EURL-FCM had developed and validated an analytical method based on HPLC-UV to monitor the homogeneity and stability of the target oligomers in the PT test items and to determine the respective assigned values, as prescribed in ISO 17043, 2010ISO 17043, 2010. The standard operating procedure of the method was provided to the participants and could be used instead of their own routine methods. Laboratory results were rated using z, z' and ζ scores in accordance with ISO 13528, 2015. The standard deviation for proficiency assessment, σ(pt), was set to 20 % of the respective assigned value, for all the four studied oligomers, based on the perception of experts. A total of 36 participants from 26 countries have registered to the exercise. They received two test items. Solution 1 consisted of food simulant D1 fortified with a known mass fraction of the four oligomers, while Solution 2 was obtained by a migration experiment with PET bottles and food simulant D1 and further fortification of the resulting solution with the four oligomers. The majority of the participating laboratories presented satisfactory results for the four PET and PBT oligomers. For the analysis of Solution 1, 79–88 % of the participants obtained |z (or z')-scores| below 2, while the satisfactory performances ranged from 71 to 85 % for Solution 2. This PT has been organised for the first time at EU level for the analysis of polyester oligomers and confirms that most of the NRLs are able to monitor properly these oligomers in the frame of Regulation (EU) No 10/2011.
format Online
Article
Text
id pubmed-6988440
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher Elsevier
record_format MEDLINE/PubMed
spelling pubmed-69884402020-03-01 Proficiency test on the determination of polyethylene and polybutylene terephthalate cyclic oligomers in a food simulant Tsochatzis, Emmanouil D. Alberto Lopes, Joao Dehouck, Pieter Robouch, Piotr Hoekstra, Eddo Food Packag Shelf Life Article The outcome of a proficiency test (PT) organised by the European Union Reference Laboratory for Food Contact Materials (EURL-FCM) is presented. The PT was set up to assess the analytical performance of National Reference Laboratories (NRLs) and Official Control Laboratories (OCLs) in the determination of mass fractions of polyethylene terephthalate (PET) and polybutylene terephthalate (PBT) cyclic dimers and trimers in the official food simulant D1 containing ethanol and water (50:50 v/v). The EURL-FCM had developed and validated an analytical method based on HPLC-UV to monitor the homogeneity and stability of the target oligomers in the PT test items and to determine the respective assigned values, as prescribed in ISO 17043, 2010ISO 17043, 2010. The standard operating procedure of the method was provided to the participants and could be used instead of their own routine methods. Laboratory results were rated using z, z' and ζ scores in accordance with ISO 13528, 2015. The standard deviation for proficiency assessment, σ(pt), was set to 20 % of the respective assigned value, for all the four studied oligomers, based on the perception of experts. A total of 36 participants from 26 countries have registered to the exercise. They received two test items. Solution 1 consisted of food simulant D1 fortified with a known mass fraction of the four oligomers, while Solution 2 was obtained by a migration experiment with PET bottles and food simulant D1 and further fortification of the resulting solution with the four oligomers. The majority of the participating laboratories presented satisfactory results for the four PET and PBT oligomers. For the analysis of Solution 1, 79–88 % of the participants obtained |z (or z')-scores| below 2, while the satisfactory performances ranged from 71 to 85 % for Solution 2. This PT has been organised for the first time at EU level for the analysis of polyester oligomers and confirms that most of the NRLs are able to monitor properly these oligomers in the frame of Regulation (EU) No 10/2011. Elsevier 2020-03 /pmc/articles/PMC6988440/ /pubmed/32128312 http://dx.doi.org/10.1016/j.fpsl.2019.100441 Text en © 2019 The Authors http://creativecommons.org/licenses/by/4.0/ This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Tsochatzis, Emmanouil D.
Alberto Lopes, Joao
Dehouck, Pieter
Robouch, Piotr
Hoekstra, Eddo
Proficiency test on the determination of polyethylene and polybutylene terephthalate cyclic oligomers in a food simulant
title Proficiency test on the determination of polyethylene and polybutylene terephthalate cyclic oligomers in a food simulant
title_full Proficiency test on the determination of polyethylene and polybutylene terephthalate cyclic oligomers in a food simulant
title_fullStr Proficiency test on the determination of polyethylene and polybutylene terephthalate cyclic oligomers in a food simulant
title_full_unstemmed Proficiency test on the determination of polyethylene and polybutylene terephthalate cyclic oligomers in a food simulant
title_short Proficiency test on the determination of polyethylene and polybutylene terephthalate cyclic oligomers in a food simulant
title_sort proficiency test on the determination of polyethylene and polybutylene terephthalate cyclic oligomers in a food simulant
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6988440/
https://www.ncbi.nlm.nih.gov/pubmed/32128312
http://dx.doi.org/10.1016/j.fpsl.2019.100441
work_keys_str_mv AT tsochatzisemmanouild proficiencytestonthedeterminationofpolyethyleneandpolybutyleneterephthalatecyclicoligomersinafoodsimulant
AT albertolopesjoao proficiencytestonthedeterminationofpolyethyleneandpolybutyleneterephthalatecyclicoligomersinafoodsimulant
AT dehouckpieter proficiencytestonthedeterminationofpolyethyleneandpolybutyleneterephthalatecyclicoligomersinafoodsimulant
AT robouchpiotr proficiencytestonthedeterminationofpolyethyleneandpolybutyleneterephthalatecyclicoligomersinafoodsimulant
AT hoekstraeddo proficiencytestonthedeterminationofpolyethyleneandpolybutyleneterephthalatecyclicoligomersinafoodsimulant