Iron(II)/Persulfate Mediated Newman–Kwart Rearrangement

[Image: see text] Herein, we report that iron(II)/ammonium persulfate in aqueous acetonitrile mediates the Newman–Kwart rearrangement of O-aryl carbamothioates. Electron-rich substrates react rapidly under moderate heating to afford the rearranged products in excellent yields. The mild conditions, r...

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Detalles Bibliográficos
Autores principales: Gendron, Thibault, Pereira, Raul, Abdi, Hafsa Y., Witney, Timothy H., Årstad, Erik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6989215/
https://www.ncbi.nlm.nih.gov/pubmed/31851521
http://dx.doi.org/10.1021/acs.orglett.9b04280

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6989215/
https://www.ncbi.nlm.nih.gov/pubmed/31851521
http://dx.doi.org/10.1021/acs.orglett.9b04280

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