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Highly Chemoselective Hydroboration of Alkynes and Nitriles Catalyzed by Group 4 Metal Amidophosphine–Borane Complexes
[Image: see text] We report a series of titanium and zirconium complexes supported by dianionic amidophosphine–borane ligands, synthesized by amine elimination and salt metathesis reactions. The Ti(IV) complex [{Ph(2)P(BH(3))N}(2)C(6)H(4)Ti(NMe(2))(2)] (1) was obtained by the reaction between tetrak...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6990649/ https://www.ncbi.nlm.nih.gov/pubmed/32010834 http://dx.doi.org/10.1021/acsomega.9b03598 |