ROMPI-CDSA: ring-opening metathesis polymerization-induced crystallization-driven self-assembly of metallo-block copolymers

Polymerization-induced self-assembly (PISA) and crystallization-driven self-assembly (CDSA) are among the most prevailing methods for block copolymer self-assembly. Taking the merits of scalability of PISA and dimension control of CDSA, we report one-pot synchronous PISA and CDSA via ring-opening me...

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Autores principales: Sha, Ye, Rahman, Md Anisur, Zhu, Tianyu, Cha, Yujin, McAlister, C. Wayne, Tang, Chuanbing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6993615/
https://www.ncbi.nlm.nih.gov/pubmed/32055347
http://dx.doi.org/10.1039/c9sc03056e
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author Sha, Ye
Rahman, Md Anisur
Zhu, Tianyu
Cha, Yujin
McAlister, C. Wayne
Tang, Chuanbing
author_facet Sha, Ye
Rahman, Md Anisur
Zhu, Tianyu
Cha, Yujin
McAlister, C. Wayne
Tang, Chuanbing
author_sort Sha, Ye
collection PubMed
description Polymerization-induced self-assembly (PISA) and crystallization-driven self-assembly (CDSA) are among the most prevailing methods for block copolymer self-assembly. Taking the merits of scalability of PISA and dimension control of CDSA, we report one-pot synchronous PISA and CDSA via ring-opening metathesis polymerization (ROMP) to prepare nano-objects based on a crystalline poly(ruthenocene) motif. We denote this self-assembly methodology as ROMPI-CDSA to enable a simple, yet robust approach for the preparation of functional nanomaterials.
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spelling pubmed-69936152020-02-13 ROMPI-CDSA: ring-opening metathesis polymerization-induced crystallization-driven self-assembly of metallo-block copolymers Sha, Ye Rahman, Md Anisur Zhu, Tianyu Cha, Yujin McAlister, C. Wayne Tang, Chuanbing Chem Sci Chemistry Polymerization-induced self-assembly (PISA) and crystallization-driven self-assembly (CDSA) are among the most prevailing methods for block copolymer self-assembly. Taking the merits of scalability of PISA and dimension control of CDSA, we report one-pot synchronous PISA and CDSA via ring-opening metathesis polymerization (ROMP) to prepare nano-objects based on a crystalline poly(ruthenocene) motif. We denote this self-assembly methodology as ROMPI-CDSA to enable a simple, yet robust approach for the preparation of functional nanomaterials. Royal Society of Chemistry 2019-09-04 /pmc/articles/PMC6993615/ /pubmed/32055347 http://dx.doi.org/10.1039/c9sc03056e Text en This journal is © The Royal Society of Chemistry 2019 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Sha, Ye
Rahman, Md Anisur
Zhu, Tianyu
Cha, Yujin
McAlister, C. Wayne
Tang, Chuanbing
ROMPI-CDSA: ring-opening metathesis polymerization-induced crystallization-driven self-assembly of metallo-block copolymers
title ROMPI-CDSA: ring-opening metathesis polymerization-induced crystallization-driven self-assembly of metallo-block copolymers
title_full ROMPI-CDSA: ring-opening metathesis polymerization-induced crystallization-driven self-assembly of metallo-block copolymers
title_fullStr ROMPI-CDSA: ring-opening metathesis polymerization-induced crystallization-driven self-assembly of metallo-block copolymers
title_full_unstemmed ROMPI-CDSA: ring-opening metathesis polymerization-induced crystallization-driven self-assembly of metallo-block copolymers
title_short ROMPI-CDSA: ring-opening metathesis polymerization-induced crystallization-driven self-assembly of metallo-block copolymers
title_sort rompi-cdsa: ring-opening metathesis polymerization-induced crystallization-driven self-assembly of metallo-block copolymers
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6993615/
https://www.ncbi.nlm.nih.gov/pubmed/32055347
http://dx.doi.org/10.1039/c9sc03056e
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