Cargando…
Planarization‐Induced Activation Wavelength Red‐Shift and Thermal Half‐Life Acceleration in Hydrazone Photoswitches
The optimization and modulation of the properties of photochromic compounds, such as their activation wavelengths and thermal relaxation half‐lives (τ (1/2)), are essential for their adaptation in various applications. In this work, we studied the effect of co‐planarization of the rotary fragment of...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6996581/ https://www.ncbi.nlm.nih.gov/pubmed/32025464 http://dx.doi.org/10.1002/open.201900340 |
_version_ | 1783493538072231936 |
---|---|
author | Shao, Baihao Aprahamian, Ivan |
author_facet | Shao, Baihao Aprahamian, Ivan |
author_sort | Shao, Baihao |
collection | PubMed |
description | The optimization and modulation of the properties of photochromic compounds, such as their activation wavelengths and thermal relaxation half‐lives (τ (1/2)), are essential for their adaptation in various applications. In this work, we studied the effect of co‐planarization of the rotary fragment of two photochromic hydrazones with the core of the molecule on their switching properties. The Z and E isomers of both compounds exhibit red‐shifted absorption bands relative to their twisted versions, allowing for their photoswitching using longer wavelengths of light. Additionally, the thermal half‐lives of both hydrazones are drastically shortened from hundreds of years to days. |
format | Online Article Text |
id | pubmed-6996581 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-69965812020-02-05 Planarization‐Induced Activation Wavelength Red‐Shift and Thermal Half‐Life Acceleration in Hydrazone Photoswitches Shao, Baihao Aprahamian, Ivan ChemistryOpen Communications The optimization and modulation of the properties of photochromic compounds, such as their activation wavelengths and thermal relaxation half‐lives (τ (1/2)), are essential for their adaptation in various applications. In this work, we studied the effect of co‐planarization of the rotary fragment of two photochromic hydrazones with the core of the molecule on their switching properties. The Z and E isomers of both compounds exhibit red‐shifted absorption bands relative to their twisted versions, allowing for their photoswitching using longer wavelengths of light. Additionally, the thermal half‐lives of both hydrazones are drastically shortened from hundreds of years to days. John Wiley and Sons Inc. 2020-02-03 /pmc/articles/PMC6996581/ /pubmed/32025464 http://dx.doi.org/10.1002/open.201900340 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. |
spellingShingle | Communications Shao, Baihao Aprahamian, Ivan Planarization‐Induced Activation Wavelength Red‐Shift and Thermal Half‐Life Acceleration in Hydrazone Photoswitches |
title | Planarization‐Induced Activation Wavelength Red‐Shift and Thermal Half‐Life Acceleration in Hydrazone Photoswitches |
title_full | Planarization‐Induced Activation Wavelength Red‐Shift and Thermal Half‐Life Acceleration in Hydrazone Photoswitches |
title_fullStr | Planarization‐Induced Activation Wavelength Red‐Shift and Thermal Half‐Life Acceleration in Hydrazone Photoswitches |
title_full_unstemmed | Planarization‐Induced Activation Wavelength Red‐Shift and Thermal Half‐Life Acceleration in Hydrazone Photoswitches |
title_short | Planarization‐Induced Activation Wavelength Red‐Shift and Thermal Half‐Life Acceleration in Hydrazone Photoswitches |
title_sort | planarization‐induced activation wavelength red‐shift and thermal half‐life acceleration in hydrazone photoswitches |
topic | Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6996581/ https://www.ncbi.nlm.nih.gov/pubmed/32025464 http://dx.doi.org/10.1002/open.201900340 |
work_keys_str_mv | AT shaobaihao planarizationinducedactivationwavelengthredshiftandthermalhalflifeaccelerationinhydrazonephotoswitches AT aprahamianivan planarizationinducedactivationwavelengthredshiftandthermalhalflifeaccelerationinhydrazonephotoswitches |