Crystal structure of di-μ-tri­hydro­(penta­fluoro­phenyl)­borato-tetra­kis­(tetra­hydro­furan)­disodium

The title compound, [Na(μ-C(6)F(5)BH(3))(C(4)H(8)O)(2)](2), represents a dimeric structure of sodium and organoborohydride, located about a centre of inversion. The Na⋯B distances of 2.7845 (19) and 2.7494 (18) Å were apparently longer than the Li⋯B distances (2.403–2.537 Å) of the lithium organotri...

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Detalles Bibliográficos
Autores principales: Tanaka, Ryo, Shiono, Takeshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001818/
https://www.ncbi.nlm.nih.gov/pubmed/32071737
http://dx.doi.org/10.1107/S2056989019017201
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author Tanaka, Ryo
Shiono, Takeshi
author_facet Tanaka, Ryo
Shiono, Takeshi
author_sort Tanaka, Ryo
collection PubMed
description The title compound, [Na(μ-C(6)F(5)BH(3))(C(4)H(8)O)(2)](2), represents a dimeric structure of sodium and organoborohydride, located about a centre of inversion. The Na⋯B distances of 2.7845 (19) and 2.7494 (18) Å were apparently longer than the Li⋯B distances (2.403–2.537 Å) of the lithium organotri­hydro­borates in the previous reports. Moreover, an inter­action between the sodium atom and one fluorine atom on the 2-position of the benzene ring is observed [Na—F = 2.6373 (12) Å]. In the crystal, the dimeric mol­ecules are stacked along the b-axis via a π–π inter­action between the benzene rings.
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spelling pubmed-70018182020-02-18 Crystal structure of di-μ-tri­hydro­(penta­fluoro­phenyl)­borato-tetra­kis­(tetra­hydro­furan)­disodium Tanaka, Ryo Shiono, Takeshi Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Na(μ-C(6)F(5)BH(3))(C(4)H(8)O)(2)](2), represents a dimeric structure of sodium and organoborohydride, located about a centre of inversion. The Na⋯B distances of 2.7845 (19) and 2.7494 (18) Å were apparently longer than the Li⋯B distances (2.403–2.537 Å) of the lithium organotri­hydro­borates in the previous reports. Moreover, an inter­action between the sodium atom and one fluorine atom on the 2-position of the benzene ring is observed [Na—F = 2.6373 (12) Å]. In the crystal, the dimeric mol­ecules are stacked along the b-axis via a π–π inter­action between the benzene rings. International Union of Crystallography 2020-01-07 /pmc/articles/PMC7001818/ /pubmed/32071737 http://dx.doi.org/10.1107/S2056989019017201 Text en © Tanaka and Shiono 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Tanaka, Ryo
Shiono, Takeshi
Crystal structure of di-μ-tri­hydro­(penta­fluoro­phenyl)­borato-tetra­kis­(tetra­hydro­furan)­disodium
title Crystal structure of di-μ-tri­hydro­(penta­fluoro­phenyl)­borato-tetra­kis­(tetra­hydro­furan)­disodium
title_full Crystal structure of di-μ-tri­hydro­(penta­fluoro­phenyl)­borato-tetra­kis­(tetra­hydro­furan)­disodium
title_fullStr Crystal structure of di-μ-tri­hydro­(penta­fluoro­phenyl)­borato-tetra­kis­(tetra­hydro­furan)­disodium
title_full_unstemmed Crystal structure of di-μ-tri­hydro­(penta­fluoro­phenyl)­borato-tetra­kis­(tetra­hydro­furan)­disodium
title_short Crystal structure of di-μ-tri­hydro­(penta­fluoro­phenyl)­borato-tetra­kis­(tetra­hydro­furan)­disodium
title_sort crystal structure of di-μ-tri­hydro­(penta­fluoro­phenyl)­borato-tetra­kis­(tetra­hydro­furan)­disodium
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001818/
https://www.ncbi.nlm.nih.gov/pubmed/32071737
http://dx.doi.org/10.1107/S2056989019017201
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