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Crystal structure of strontium thiosulfate monohydrate
SrS(2)O(3)·H(2)O was obtained from an aqueous solution of Na(2)S(2)O(3) and Sr(NO(3))(2) and crystallizes in space group P [Image: see text] with all atoms at general positions. The Sr(2+) ion exhibits an [8 + 1] coordination defined by two terminal S and six O atoms of thiosulfate ions, one of the...
Autor principal: | |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001820/ https://www.ncbi.nlm.nih.gov/pubmed/32071746 http://dx.doi.org/10.1107/S2056989020000353 |
Sumario: | SrS(2)O(3)·H(2)O was obtained from an aqueous solution of Na(2)S(2)O(3) and Sr(NO(3))(2) and crystallizes in space group P [Image: see text] with all atoms at general positions. The Sr(2+) ion exhibits an [8 + 1] coordination defined by two terminal S and six O atoms of thiosulfate ions, one of the latter at a longer distance, and by one O atom of a water molecule. Two thiosulfate anions act as bidentate, four as monodentate ligands. The structure consists of mainly ionically interacting layers lying parallel to the crystallographic ab plane. The layers are connected by O—H⋯S and O—H⋯O hydrogen bonds of moderate strength. |
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