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Crystal structure of strontium thio­sulfate monohydrate

SrS(2)O(3)·H(2)O was obtained from an aqueous solution of Na(2)S(2)O(3) and Sr(NO(3))(2) and crystallizes in space group P [Image: see text] with all atoms at general positions. The Sr(2+) ion exhibits an [8 + 1] coordination defined by two terminal S and six O atoms of thio­sulfate ions, one of the...

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Detalles Bibliográficos
Autor principal: Klein, Wilhelm
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001820/
https://www.ncbi.nlm.nih.gov/pubmed/32071746
http://dx.doi.org/10.1107/S2056989020000353
Descripción
Sumario:SrS(2)O(3)·H(2)O was obtained from an aqueous solution of Na(2)S(2)O(3) and Sr(NO(3))(2) and crystallizes in space group P [Image: see text] with all atoms at general positions. The Sr(2+) ion exhibits an [8 + 1] coordination defined by two terminal S and six O atoms of thio­sulfate ions, one of the latter at a longer distance, and by one O atom of a water mol­ecule. Two thio­sulfate anions act as bidentate, four as monodentate ligands. The structure consists of mainly ionically inter­acting layers lying parallel to the crystallographic ab plane. The layers are connected by O—H⋯S and O—H⋯O hydrogen bonds of moderate strength.