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Crystal structure of strontium thio­sulfate monohydrate

SrS(2)O(3)·H(2)O was obtained from an aqueous solution of Na(2)S(2)O(3) and Sr(NO(3))(2) and crystallizes in space group P [Image: see text] with all atoms at general positions. The Sr(2+) ion exhibits an [8 + 1] coordination defined by two terminal S and six O atoms of thio­sulfate ions, one of the...

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Autor principal: Klein, Wilhelm
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001820/
https://www.ncbi.nlm.nih.gov/pubmed/32071746
http://dx.doi.org/10.1107/S2056989020000353
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author Klein, Wilhelm
author_facet Klein, Wilhelm
author_sort Klein, Wilhelm
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description SrS(2)O(3)·H(2)O was obtained from an aqueous solution of Na(2)S(2)O(3) and Sr(NO(3))(2) and crystallizes in space group P [Image: see text] with all atoms at general positions. The Sr(2+) ion exhibits an [8 + 1] coordination defined by two terminal S and six O atoms of thio­sulfate ions, one of the latter at a longer distance, and by one O atom of a water mol­ecule. Two thio­sulfate anions act as bidentate, four as monodentate ligands. The structure consists of mainly ionically inter­acting layers lying parallel to the crystallographic ab plane. The layers are connected by O—H⋯S and O—H⋯O hydrogen bonds of moderate strength.
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spelling pubmed-70018202020-02-18 Crystal structure of strontium thio­sulfate monohydrate Klein, Wilhelm Acta Crystallogr E Crystallogr Commun Research Communications SrS(2)O(3)·H(2)O was obtained from an aqueous solution of Na(2)S(2)O(3) and Sr(NO(3))(2) and crystallizes in space group P [Image: see text] with all atoms at general positions. The Sr(2+) ion exhibits an [8 + 1] coordination defined by two terminal S and six O atoms of thio­sulfate ions, one of the latter at a longer distance, and by one O atom of a water mol­ecule. Two thio­sulfate anions act as bidentate, four as monodentate ligands. The structure consists of mainly ionically inter­acting layers lying parallel to the crystallographic ab plane. The layers are connected by O—H⋯S and O—H⋯O hydrogen bonds of moderate strength. International Union of Crystallography 2020-01-17 /pmc/articles/PMC7001820/ /pubmed/32071746 http://dx.doi.org/10.1107/S2056989020000353 Text en © Wilhelm Klein 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Klein, Wilhelm
Crystal structure of strontium thio­sulfate monohydrate
title Crystal structure of strontium thio­sulfate monohydrate
title_full Crystal structure of strontium thio­sulfate monohydrate
title_fullStr Crystal structure of strontium thio­sulfate monohydrate
title_full_unstemmed Crystal structure of strontium thio­sulfate monohydrate
title_short Crystal structure of strontium thio­sulfate monohydrate
title_sort crystal structure of strontium thio­sulfate monohydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001820/
https://www.ncbi.nlm.nih.gov/pubmed/32071746
http://dx.doi.org/10.1107/S2056989020000353
work_keys_str_mv AT kleinwilhelm crystalstructureofstrontiumthiosulfatemonohydrate