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Crystal structure of strontium thiosulfate monohydrate
SrS(2)O(3)·H(2)O was obtained from an aqueous solution of Na(2)S(2)O(3) and Sr(NO(3))(2) and crystallizes in space group P [Image: see text] with all atoms at general positions. The Sr(2+) ion exhibits an [8 + 1] coordination defined by two terminal S and six O atoms of thiosulfate ions, one of the...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001820/ https://www.ncbi.nlm.nih.gov/pubmed/32071746 http://dx.doi.org/10.1107/S2056989020000353 |
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author | Klein, Wilhelm |
author_facet | Klein, Wilhelm |
author_sort | Klein, Wilhelm |
collection | PubMed |
description | SrS(2)O(3)·H(2)O was obtained from an aqueous solution of Na(2)S(2)O(3) and Sr(NO(3))(2) and crystallizes in space group P [Image: see text] with all atoms at general positions. The Sr(2+) ion exhibits an [8 + 1] coordination defined by two terminal S and six O atoms of thiosulfate ions, one of the latter at a longer distance, and by one O atom of a water molecule. Two thiosulfate anions act as bidentate, four as monodentate ligands. The structure consists of mainly ionically interacting layers lying parallel to the crystallographic ab plane. The layers are connected by O—H⋯S and O—H⋯O hydrogen bonds of moderate strength. |
format | Online Article Text |
id | pubmed-7001820 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-70018202020-02-18 Crystal structure of strontium thiosulfate monohydrate Klein, Wilhelm Acta Crystallogr E Crystallogr Commun Research Communications SrS(2)O(3)·H(2)O was obtained from an aqueous solution of Na(2)S(2)O(3) and Sr(NO(3))(2) and crystallizes in space group P [Image: see text] with all atoms at general positions. The Sr(2+) ion exhibits an [8 + 1] coordination defined by two terminal S and six O atoms of thiosulfate ions, one of the latter at a longer distance, and by one O atom of a water molecule. Two thiosulfate anions act as bidentate, four as monodentate ligands. The structure consists of mainly ionically interacting layers lying parallel to the crystallographic ab plane. The layers are connected by O—H⋯S and O—H⋯O hydrogen bonds of moderate strength. International Union of Crystallography 2020-01-17 /pmc/articles/PMC7001820/ /pubmed/32071746 http://dx.doi.org/10.1107/S2056989020000353 Text en © Wilhelm Klein 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
spellingShingle | Research Communications Klein, Wilhelm Crystal structure of strontium thiosulfate monohydrate |
title | Crystal structure of strontium thiosulfate monohydrate |
title_full | Crystal structure of strontium thiosulfate monohydrate |
title_fullStr | Crystal structure of strontium thiosulfate monohydrate |
title_full_unstemmed | Crystal structure of strontium thiosulfate monohydrate |
title_short | Crystal structure of strontium thiosulfate monohydrate |
title_sort | crystal structure of strontium thiosulfate monohydrate |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001820/ https://www.ncbi.nlm.nih.gov/pubmed/32071746 http://dx.doi.org/10.1107/S2056989020000353 |
work_keys_str_mv | AT kleinwilhelm crystalstructureofstrontiumthiosulfatemonohydrate |