Crystal structure of {4-[10,15,20-tris­(4-meth­oxy­phen­yl)porphyrin-5-yl]benzyl 2-diazo­acetato}­zinc(II)

In the title compound, [Zn(C(50)H(36)N(6)O(5))], the Zn(II) cation is chelated by four pyrrole N atoms of the porphyrinate anion and coordinated by a symmetry-generated keto O atom of the diazo­ester group in a distorted square-pyramidal geometry. The mean Zn—N(pyrrole) bond length is 2.058 Å and th...

Descripción completa

Detalles Bibliográficos
Autores principales: Carrie, Daniel, Roisnel, Thierry, Simonneaux, Gerard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001825/
https://www.ncbi.nlm.nih.gov/pubmed/32071761
http://dx.doi.org/10.1107/S2056989020001085
Descripción
Sumario:In the title compound, [Zn(C(50)H(36)N(6)O(5))], the Zn(II) cation is chelated by four pyrrole N atoms of the porphyrinate anion and coordinated by a symmetry-generated keto O atom of the diazo­ester group in a distorted square-pyramidal geometry. The mean Zn—N(pyrrole) bond length is 2.058 Å and the Zn—O(diazo­ester) bond length is 2.179 (4) Å. The zinc cation is displaced by 0.2202 (13) Å from the N(4)C(20) mean plane of the porphyrinate anion toward the O atom; the involvement of this atom leads to a [100] polymeric chain in the crystal.

Ejemplares similares