Crystal structure of {4-[10,15,20-tris­(4-meth­oxy­phen­yl)porphyrin-5-yl]benzyl 2-diazo­acetato}­zinc(II)

In the title compound, [Zn(C(50)H(36)N(6)O(5))], the Zn(II) cation is chelated by four pyrrole N atoms of the porphyrinate anion and coordinated by a symmetry-generated keto O atom of the diazo­ester group in a distorted square-pyramidal geometry. The mean Zn—N(pyrrole) bond length is 2.058 Å and th...

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Detalles Bibliográficos
Autores principales: Carrie, Daniel, Roisnel, Thierry, Simonneaux, Gerard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001825/
https://www.ncbi.nlm.nih.gov/pubmed/32071761
http://dx.doi.org/10.1107/S2056989020001085
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author Carrie, Daniel
Roisnel, Thierry
Simonneaux, Gerard
author_facet Carrie, Daniel
Roisnel, Thierry
Simonneaux, Gerard
author_sort Carrie, Daniel
collection PubMed
description In the title compound, [Zn(C(50)H(36)N(6)O(5))], the Zn(II) cation is chelated by four pyrrole N atoms of the porphyrinate anion and coordinated by a symmetry-generated keto O atom of the diazo­ester group in a distorted square-pyramidal geometry. The mean Zn—N(pyrrole) bond length is 2.058 Å and the Zn—O(diazo­ester) bond length is 2.179 (4) Å. The zinc cation is displaced by 0.2202 (13) Å from the N(4)C(20) mean plane of the porphyrinate anion toward the O atom; the involvement of this atom leads to a [100] polymeric chain in the crystal.
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spelling pubmed-70018252020-02-18 Crystal structure of {4-[10,15,20-tris­(4-meth­oxy­phen­yl)porphyrin-5-yl]benzyl 2-diazo­acetato}­zinc(II) Carrie, Daniel Roisnel, Thierry Simonneaux, Gerard Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, [Zn(C(50)H(36)N(6)O(5))], the Zn(II) cation is chelated by four pyrrole N atoms of the porphyrinate anion and coordinated by a symmetry-generated keto O atom of the diazo­ester group in a distorted square-pyramidal geometry. The mean Zn—N(pyrrole) bond length is 2.058 Å and the Zn—O(diazo­ester) bond length is 2.179 (4) Å. The zinc cation is displaced by 0.2202 (13) Å from the N(4)C(20) mean plane of the porphyrinate anion toward the O atom; the involvement of this atom leads to a [100] polymeric chain in the crystal. International Union of Crystallography 2020-01-31 /pmc/articles/PMC7001825/ /pubmed/32071761 http://dx.doi.org/10.1107/S2056989020001085 Text en © Carrie et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Carrie, Daniel
Roisnel, Thierry
Simonneaux, Gerard
Crystal structure of {4-[10,15,20-tris­(4-meth­oxy­phen­yl)porphyrin-5-yl]benzyl 2-diazo­acetato}­zinc(II)
title Crystal structure of {4-[10,15,20-tris­(4-meth­oxy­phen­yl)porphyrin-5-yl]benzyl 2-diazo­acetato}­zinc(II)
title_full Crystal structure of {4-[10,15,20-tris­(4-meth­oxy­phen­yl)porphyrin-5-yl]benzyl 2-diazo­acetato}­zinc(II)
title_fullStr Crystal structure of {4-[10,15,20-tris­(4-meth­oxy­phen­yl)porphyrin-5-yl]benzyl 2-diazo­acetato}­zinc(II)
title_full_unstemmed Crystal structure of {4-[10,15,20-tris­(4-meth­oxy­phen­yl)porphyrin-5-yl]benzyl 2-diazo­acetato}­zinc(II)
title_short Crystal structure of {4-[10,15,20-tris­(4-meth­oxy­phen­yl)porphyrin-5-yl]benzyl 2-diazo­acetato}­zinc(II)
title_sort crystal structure of {4-[10,15,20-tris­(4-meth­oxy­phen­yl)porphyrin-5-yl]benzyl 2-diazo­acetato}­zinc(ii)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001825/
https://www.ncbi.nlm.nih.gov/pubmed/32071761
http://dx.doi.org/10.1107/S2056989020001085
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AT simonneauxgerard crystalstructureof4101520tris4methoxyphenylporphyrin5ylbenzyl2diazoacetatozincii

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