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Crystal structure of {4-[10,15,20-tris(4-methoxyphenyl)porphyrin-5-yl]benzyl 2-diazoacetato}zinc(II)
In the title compound, [Zn(C(50)H(36)N(6)O(5))], the Zn(II) cation is chelated by four pyrrole N atoms of the porphyrinate anion and coordinated by a symmetry-generated keto O atom of the diazoester group in a distorted square-pyramidal geometry. The mean Zn—N(pyrrole) bond length is 2.058 Å and th...
Autores principales: | Carrie, Daniel, Roisnel, Thierry, Simonneaux, Gerard |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001825/ https://www.ncbi.nlm.nih.gov/pubmed/32071761 http://dx.doi.org/10.1107/S2056989020001085 |
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