An indenide-tethered N-heterocyclic stannylene

The structure of (μ-1κN:2(η(2)),κ(2) N,N′-(2-{[2,6-bis(propan-2-yl)phen­yl]aza­nid­yl}eth­yl)[2-(1H-inden-1-yl)eth­yl]aza­nido)(1,4,7,10,13,16-hexa­oxa­cyclo­octa­dec­ane-1κ(6) O)lithiumtin, [LiSn(C(8)H(16)O(4))(C(25)H(31)N(2))], at 100 K has monoclinic (P2(1)/n) symmetry. Analysis of the coordinati...

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Autores principales: Bischof, Tobias, Evans, Kieren J., Haddow, Mairi F., Mansell, Stephen M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001827/
https://www.ncbi.nlm.nih.gov/pubmed/32071756
http://dx.doi.org/10.1107/S205698902000047X
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author Bischof, Tobias
Evans, Kieren J.
Haddow, Mairi F.
Mansell, Stephen M.
author_facet Bischof, Tobias
Evans, Kieren J.
Haddow, Mairi F.
Mansell, Stephen M.
author_sort Bischof, Tobias
collection PubMed
description The structure of (μ-1κN:2(η(2)),κ(2) N,N′-(2-{[2,6-bis(propan-2-yl)phen­yl]aza­nid­yl}eth­yl)[2-(1H-inden-1-yl)eth­yl]aza­nido)(1,4,7,10,13,16-hexa­oxa­cyclo­octa­dec­ane-1κ(6) O)lithiumtin, [LiSn(C(8)H(16)O(4))(C(25)H(31)N(2))], at 100 K has monoclinic (P2(1)/n) symmetry. Analysis of the coordination of the Sn to the indenyl ring shows that the Sn inter­acts in an η(2) fashion. A database survey showed that whilst this coordination mode is unusual for Ge and Pb compounds, Sn displays a wider range of coordination modes to cyclo­penta­dienyl ligands and their derivatives.
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spelling pubmed-70018272020-02-18 An indenide-tethered N-heterocyclic stannylene Bischof, Tobias Evans, Kieren J. Haddow, Mairi F. Mansell, Stephen M. Acta Crystallogr E Crystallogr Commun Research Communications The structure of (μ-1κN:2(η(2)),κ(2) N,N′-(2-{[2,6-bis(propan-2-yl)phen­yl]aza­nid­yl}eth­yl)[2-(1H-inden-1-yl)eth­yl]aza­nido)(1,4,7,10,13,16-hexa­oxa­cyclo­octa­dec­ane-1κ(6) O)lithiumtin, [LiSn(C(8)H(16)O(4))(C(25)H(31)N(2))], at 100 K has monoclinic (P2(1)/n) symmetry. Analysis of the coordination of the Sn to the indenyl ring shows that the Sn inter­acts in an η(2) fashion. A database survey showed that whilst this coordination mode is unusual for Ge and Pb compounds, Sn displays a wider range of coordination modes to cyclo­penta­dienyl ligands and their derivatives. International Union of Crystallography 2020-01-21 /pmc/articles/PMC7001827/ /pubmed/32071756 http://dx.doi.org/10.1107/S205698902000047X Text en © Bischof et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Bischof, Tobias
Evans, Kieren J.
Haddow, Mairi F.
Mansell, Stephen M.
An indenide-tethered N-heterocyclic stannylene
title An indenide-tethered N-heterocyclic stannylene
title_full An indenide-tethered N-heterocyclic stannylene
title_fullStr An indenide-tethered N-heterocyclic stannylene
title_full_unstemmed An indenide-tethered N-heterocyclic stannylene
title_short An indenide-tethered N-heterocyclic stannylene
title_sort indenide-tethered n-heterocyclic stannylene
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001827/
https://www.ncbi.nlm.nih.gov/pubmed/32071756
http://dx.doi.org/10.1107/S205698902000047X
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