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Tetraaqua[3-oxo-1,3-bis(pyridinium-2-yl)propan-1-olato]nickel(II) tribromide dihydrate
The crystal structure of the title compound, [Ni(C(13)H(11)N(2)O(2))(H(2)O)(4)]Br(3)·2H(2)O, contains an octahedral Ni(II) atom coordinated to the enol form of 1,3-dipyridylpropane-1,3-dione (dppo) and four water molecules. Both pyridyl rings on the ligand are protonated, forming pyridinium ring...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001841/ https://www.ncbi.nlm.nih.gov/pubmed/32071760 http://dx.doi.org/10.1107/S205698902000081X |
| _version_ | 1783494302584799232 |
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| author | Westcott, Barry L. Crundwell, Guy Alicea-Velázquez, Nilda L. |
| author_facet | Westcott, Barry L. Crundwell, Guy Alicea-Velázquez, Nilda L. |
| author_sort | Westcott, Barry L. |
| collection | PubMed |
| description | The crystal structure of the title compound, [Ni(C(13)H(11)N(2)O(2))(H(2)O)(4)]Br(3)·2H(2)O, contains an octahedral Ni(II) atom coordinated to the enol form of 1,3-dipyridylpropane-1,3-dione (dppo) and four water molecules. Both pyridyl rings on the ligand are protonated, forming pyridinium rings and creating an overall ligand charge of +1. The protonated nitrogen-containing rings are involved in hydrogen-bonding interactions with neighoring bromide anions. There are many additional hydrogen-bonding interactions involving coordinated water molecules on the Ni(II) atom, bromide anions and hydration water molecules. |
| format | Online Article Text |
| id | pubmed-7001841 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2020 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-70018412020-02-18 Tetraaqua[3-oxo-1,3-bis(pyridinium-2-yl)propan-1-olato]nickel(II) tribromide dihydrate Westcott, Barry L. Crundwell, Guy Alicea-Velázquez, Nilda L. Acta Crystallogr E Crystallogr Commun Research Communications The crystal structure of the title compound, [Ni(C(13)H(11)N(2)O(2))(H(2)O)(4)]Br(3)·2H(2)O, contains an octahedral Ni(II) atom coordinated to the enol form of 1,3-dipyridylpropane-1,3-dione (dppo) and four water molecules. Both pyridyl rings on the ligand are protonated, forming pyridinium rings and creating an overall ligand charge of +1. The protonated nitrogen-containing rings are involved in hydrogen-bonding interactions with neighoring bromide anions. There are many additional hydrogen-bonding interactions involving coordinated water molecules on the Ni(II) atom, bromide anions and hydration water molecules. International Union of Crystallography 2020-01-31 /pmc/articles/PMC7001841/ /pubmed/32071760 http://dx.doi.org/10.1107/S205698902000081X Text en © Westcott et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/ |
| spellingShingle | Research Communications Westcott, Barry L. Crundwell, Guy Alicea-Velázquez, Nilda L. Tetraaqua[3-oxo-1,3-bis(pyridinium-2-yl)propan-1-olato]nickel(II) tribromide dihydrate |
| title | Tetraaqua[3-oxo-1,3-bis(pyridinium-2-yl)propan-1-olato]nickel(II) tribromide dihydrate |
| title_full | Tetraaqua[3-oxo-1,3-bis(pyridinium-2-yl)propan-1-olato]nickel(II) tribromide dihydrate |
| title_fullStr | Tetraaqua[3-oxo-1,3-bis(pyridinium-2-yl)propan-1-olato]nickel(II) tribromide dihydrate |
| title_full_unstemmed | Tetraaqua[3-oxo-1,3-bis(pyridinium-2-yl)propan-1-olato]nickel(II) tribromide dihydrate |
| title_short | Tetraaqua[3-oxo-1,3-bis(pyridinium-2-yl)propan-1-olato]nickel(II) tribromide dihydrate |
| title_sort | tetraaqua[3-oxo-1,3-bis(pyridinium-2-yl)propan-1-olato]nickel(ii) tribromide dihydrate |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001841/ https://www.ncbi.nlm.nih.gov/pubmed/32071760 http://dx.doi.org/10.1107/S205698902000081X |
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