A new pseudopolymorph of perchlorinated neo­penta­silane: the benzene monosolvate Si(SiCl(3))(4)·C(6)H(6)

A new pseudopolymorph of dodeca­chloro­penta­silane, namely a benzene monosolvate, Si(5)Cl(12)·C(6)H(6), is described. There are two half mol­ecules of each kind in the asymmetric unit. Both Si(5)Cl(12) mol­ecules are completed by crystallographic twofold symmetry. One of the benzene mol­ecules is l...

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Autores principales: Tillmann, Jan, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001847/
https://www.ncbi.nlm.nih.gov/pubmed/32071758
http://dx.doi.org/10.1107/S2056989020000900
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author Tillmann, Jan
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Tillmann, Jan
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Tillmann, Jan
collection PubMed
description A new pseudopolymorph of dodeca­chloro­penta­silane, namely a benzene monosolvate, Si(5)Cl(12)·C(6)H(6), is described. There are two half mol­ecules of each kind in the asymmetric unit. Both Si(5)Cl(12) mol­ecules are completed by crystallographic twofold symmetry. One of the benzene mol­ecules is located on a twofold rotation axis with two C—H groups located on this rotation axis. The second benzene mol­ecule has all atoms on a general position: it is disordered over two equally occupied orientations. No directional inter­actions beyond normal van der Waals contacts occur in the crystal.
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spelling pubmed-70018472020-02-18 A new pseudopolymorph of perchlorinated neo­penta­silane: the benzene monosolvate Si(SiCl(3))(4)·C(6)H(6) Tillmann, Jan Lerner, Hans-Wolfram Bolte, Michael Acta Crystallogr E Crystallogr Commun Research Communications A new pseudopolymorph of dodeca­chloro­penta­silane, namely a benzene monosolvate, Si(5)Cl(12)·C(6)H(6), is described. There are two half mol­ecules of each kind in the asymmetric unit. Both Si(5)Cl(12) mol­ecules are completed by crystallographic twofold symmetry. One of the benzene mol­ecules is located on a twofold rotation axis with two C—H groups located on this rotation axis. The second benzene mol­ecule has all atoms on a general position: it is disordered over two equally occupied orientations. No directional inter­actions beyond normal van der Waals contacts occur in the crystal. International Union of Crystallography 2020-01-31 /pmc/articles/PMC7001847/ /pubmed/32071758 http://dx.doi.org/10.1107/S2056989020000900 Text en © Tillmann et al. 2020 http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/4.0/
spellingShingle Research Communications
Tillmann, Jan
Lerner, Hans-Wolfram
Bolte, Michael
A new pseudopolymorph of perchlorinated neo­penta­silane: the benzene monosolvate Si(SiCl(3))(4)·C(6)H(6)
title A new pseudopolymorph of perchlorinated neo­penta­silane: the benzene monosolvate Si(SiCl(3))(4)·C(6)H(6)
title_full A new pseudopolymorph of perchlorinated neo­penta­silane: the benzene monosolvate Si(SiCl(3))(4)·C(6)H(6)
title_fullStr A new pseudopolymorph of perchlorinated neo­penta­silane: the benzene monosolvate Si(SiCl(3))(4)·C(6)H(6)
title_full_unstemmed A new pseudopolymorph of perchlorinated neo­penta­silane: the benzene monosolvate Si(SiCl(3))(4)·C(6)H(6)
title_short A new pseudopolymorph of perchlorinated neo­penta­silane: the benzene monosolvate Si(SiCl(3))(4)·C(6)H(6)
title_sort new pseudopolymorph of perchlorinated neo­penta­silane: the benzene monosolvate si(sicl(3))(4)·c(6)h(6)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001847/
https://www.ncbi.nlm.nih.gov/pubmed/32071758
http://dx.doi.org/10.1107/S2056989020000900
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