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Design of Rubber Composites with Autonomous Self-Healing Capability

[Image: see text] The development of self-healing rubbers is currently under investigation as a strategy to promote their reuse and, hence, reduce their waste. However, autonomous, multicycle self-healing rubbers with good mechanical properties have so far proven difficult to achieve. Here, mechanic...

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Detalles Bibliográficos
Autores principales: Utrera-Barrios, Saul, Hernández Santana, Marianella, Verdejo, Raquel, López-Manchado, Miguel A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003207/
https://www.ncbi.nlm.nih.gov/pubmed/32039326
http://dx.doi.org/10.1021/acsomega.9b03516
Descripción
Sumario:[Image: see text] The development of self-healing rubbers is currently under investigation as a strategy to promote their reuse and, hence, reduce their waste. However, autonomous, multicycle self-healing rubbers with good mechanical properties have so far proven difficult to achieve. Here, mechanically robust composites based on epoxidized natural rubber (ENR) and thermally reduced graphene oxide (TRGO) were successfully designed and prepared with a high healing efficiency of up to 85% at room temperature without applying external stimuli. The incorporation of TRGO not only improves the mechanical performance in more than 100% in relation to pristine ENR but also promotes the hydrogen bonding interactions with the rubber. This leads to a homogenous dispersion of TRGO within the ENR matrix, which further increases its self-healing capability.