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The Bis(ferrocenyl)phosphenium Ion Revisited
The bis(ferrocenyl)phosphenium ion, [Fc(2)P](+), reported by Cowley et al. (J. Am. Chem. Soc. 1981, 103, 714–715), was the only claimed donor‐free divalent phosphenium ion. Our examination of the molecular and electronic structure reveals that [Fc(2)P](+) possesses significant intramolecular Fe⋅⋅⋅P...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003730/ https://www.ncbi.nlm.nih.gov/pubmed/31751492 http://dx.doi.org/10.1002/anie.201913081 |