A Highly Asymmetric Gold(III) η(3)‐Allyl Complex

A highly asymmetric Au(III) η(3)‐allyl complex has been generated by treating Au(η(1)‐allyl)Br(tpy) (tpy=2‐(p‐tolyl)pyridine) with AgNTf(2). The resulting η(3)‐allyl complex has been characterized by NMR spectroscopy and X‐ray crystallography. DFT calculations and variable temperature (1)H NMR sugge...

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Detalles Bibliográficos
Autores principales: Holmsen, Marte Sofie Martinsen, Nova, Ainara, Øien‐Ødegaard, Sigurd, Heyn, Richard H., Tilset, Mats
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003771/
https://www.ncbi.nlm.nih.gov/pubmed/31710154
http://dx.doi.org/10.1002/anie.201912315
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author Holmsen, Marte Sofie Martinsen
Nova, Ainara
Øien‐Ødegaard, Sigurd
Heyn, Richard H.
Tilset, Mats
author_facet Holmsen, Marte Sofie Martinsen
Nova, Ainara
Øien‐Ødegaard, Sigurd
Heyn, Richard H.
Tilset, Mats
author_sort Holmsen, Marte Sofie Martinsen
collection PubMed
description A highly asymmetric Au(III) η(3)‐allyl complex has been generated by treating Au(η(1)‐allyl)Br(tpy) (tpy=2‐(p‐tolyl)pyridine) with AgNTf(2). The resulting η(3)‐allyl complex has been characterized by NMR spectroscopy and X‐ray crystallography. DFT calculations and variable temperature (1)H NMR suggest that the allyl ligand is highly fluxional.
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spelling pubmed-70037712020-02-10 A Highly Asymmetric Gold(III) η(3)‐Allyl Complex Holmsen, Marte Sofie Martinsen Nova, Ainara Øien‐Ødegaard, Sigurd Heyn, Richard H. Tilset, Mats Angew Chem Int Ed Engl Communications A highly asymmetric Au(III) η(3)‐allyl complex has been generated by treating Au(η(1)‐allyl)Br(tpy) (tpy=2‐(p‐tolyl)pyridine) with AgNTf(2). The resulting η(3)‐allyl complex has been characterized by NMR spectroscopy and X‐ray crystallography. DFT calculations and variable temperature (1)H NMR suggest that the allyl ligand is highly fluxional. John Wiley and Sons Inc. 2019-12-12 2020-01-20 /pmc/articles/PMC7003771/ /pubmed/31710154 http://dx.doi.org/10.1002/anie.201912315 Text en © 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Holmsen, Marte Sofie Martinsen
Nova, Ainara
Øien‐Ødegaard, Sigurd
Heyn, Richard H.
Tilset, Mats
A Highly Asymmetric Gold(III) η(3)‐Allyl Complex
title A Highly Asymmetric Gold(III) η(3)‐Allyl Complex
title_full A Highly Asymmetric Gold(III) η(3)‐Allyl Complex
title_fullStr A Highly Asymmetric Gold(III) η(3)‐Allyl Complex
title_full_unstemmed A Highly Asymmetric Gold(III) η(3)‐Allyl Complex
title_short A Highly Asymmetric Gold(III) η(3)‐Allyl Complex
title_sort highly asymmetric gold(iii) η(3)‐allyl complex
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003771/
https://www.ncbi.nlm.nih.gov/pubmed/31710154
http://dx.doi.org/10.1002/anie.201912315
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