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A Highly Asymmetric Gold(III) η(3)‐Allyl Complex

A highly asymmetric Au(III) η(3)‐allyl complex has been generated by treating Au(η(1)‐allyl)Br(tpy) (tpy=2‐(p‐tolyl)pyridine) with AgNTf(2). The resulting η(3)‐allyl complex has been characterized by NMR spectroscopy and X‐ray crystallography. DFT calculations and variable temperature (1)H NMR sugge...

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Detalles Bibliográficos
Autores principales:	Holmsen, Marte Sofie Martinsen, Nova, Ainara, Øien‐Ødegaard, Sigurd, Heyn, Richard H., Tilset, Mats
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2019
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003771/ https://www.ncbi.nlm.nih.gov/pubmed/31710154 http://dx.doi.org/10.1002/anie.201912315

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