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Efficient Organocatalytic Dehydrogenation of Ammonia Borane

Dehydrogenation of ammonia borane by sterically encumbered pyridones as organocatalysts is reported. With 6‐tert‐butyl‐2‐thiopyridone as the catalyst, a turnover frequency (TOF) of 88 h(−1) was achieved. Experimental mechanistic investigations, substantiated by DLPNO‐CCSD(T) computations, indicate a...

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Detalles Bibliográficos
Autores principales:	Hasenbeck, Max, Becker, Jonathan, Gellrich, Urs
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2019
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003781/ https://www.ncbi.nlm.nih.gov/pubmed/31573726 http://dx.doi.org/10.1002/anie.201910636

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