The Critical Role of Reductive Steps in the Nickel‐Catalyzed Hydrogenolysis and Hydrolysis of Aryl Ether C−O Bonds

The hydrogenolysis of the aromatic C−O bond in aryl ethers catalyzed by Ni was studied in decalin and water. Observations of a significant kinetic isotope effect (k (H)/k (D)=5.7) for the reactions of diphenyl ether under H(2) and D(2) atmosphere and a positive dependence of the rate on H(2) chemica...

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Detalles Bibliográficos
Autores principales: Wang, Meng, Zhao, Yuntao, Mei, Donghai, Bullock, R. Morris, Gutiérrez, Oliver Y., Camaioni, Donald M., Lercher, Johannes A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003888/
https://www.ncbi.nlm.nih.gov/pubmed/31512341
http://dx.doi.org/10.1002/anie.201909551

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003888/
https://www.ncbi.nlm.nih.gov/pubmed/31512341
http://dx.doi.org/10.1002/anie.201909551

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