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First experimental evidence for the elusive tetrahedral cations [EP(3)](+) (E = S, Se, Te) in the condensed phase
Condensed phase access to the unprecedented tetrahedral cations [EP(3)](+) (E = S, Se, Te) was achieved through the reaction of ECl(3)[WCA] with white phosphorus ([WCA](–) = [Al(OR(F))(4)](–) and [F(Al(OR(F))(3))(2)](–); –R(F) = –C(CF(3))(3)). Previously, [EP(3)](+) was only known from gas phase MS...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7006506/ https://www.ncbi.nlm.nih.gov/pubmed/32055385 http://dx.doi.org/10.1039/c9sc03915e |