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Divergent Catalytic Strategies for the Cis/Trans Stereoselective Ring-Opening Polymerization of a Dual Cyclic Carbonate/Olefin Monomer
[Image: see text] A dual seven-membered cyclic carbonate/olefin monomer was synthesized from CO(2) and cis-1,4-butenediol and polymerized. The properties of the polymer were controlled using divergent catalytic strategies toward the stereochemistry of the olefin. Ring-opening polymerization of the c...
Autores principales: | McGuire, Thomas M., Pérale, Cécile, Castaing, Rémi, Kociok-Köhn, Gabriele, Buchard, Antoine |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2019
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7007229/ https://www.ncbi.nlm.nih.gov/pubmed/31429566 http://dx.doi.org/10.1021/jacs.9b06259 |
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