Formation of a Copper(II)–Tyrosyl Complex at the Active Site of Lytic Polysaccharide Monooxygenases Following Oxidation by H(2)O(2)

[Image: see text] Hydrogen peroxide is a cosubstrate for the oxidative cleavage of saccharidic substrates by copper-containing lytic polysaccharide monooxygenases (LPMOs). The rate of reaction of LPMOs with hydrogen peroxide is high, but it is accompanied by rapid inactivation of the enzymes, presum...

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Detalles Bibliográficos
Autores principales: Paradisi, Alessandro, Johnston, Esther M., Tovborg, Morten, Nicoll, Callum R., Ciano, Luisa, Dowle, Adam, McMaster, Jonathan, Hancock, Y., Davies, Gideon J., Walton, Paul H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7007232/
https://www.ncbi.nlm.nih.gov/pubmed/31675221
http://dx.doi.org/10.1021/jacs.9b09833

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