Meroterpenoid Synthesis via Sequential Polyketide Aromatization and Radical Anion Cascade Triene Cyclization: Biomimetic Total Syntheses of Austalide Natural Products

[Image: see text] The first total synthesis of five austalide natural products, (±)-17S-dihydroaustalide K, (±)-austalide K, (±)-13-deacetoxyaustalide I, (±)-austalide P, and (±)-13-deoxyaustalide Q acid, was accomplished via a series of biomimetic transformations. Key steps involved polyketide arom...

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Detalles Bibliográficos
Autores principales: Ma, Tsz-Kan, Parsons, Philip J., Barrett, Anthony G. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7007238/
https://www.ncbi.nlm.nih.gov/pubmed/30938997
http://dx.doi.org/10.1021/acs.joc.9b00142

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7007238/
https://www.ncbi.nlm.nih.gov/pubmed/30938997
http://dx.doi.org/10.1021/acs.joc.9b00142

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