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Unravelling the Photochemical Transformations of Chromium(I) 1,3 Bis(diphenylphosphino), [Cr(CO)(4)(dppp)](+), by EPR Spectroscopy

[Image: see text] UV-induced photochemical transformations of the paramagnetic [Cr(CO)(4)(Ph(2)PCH(2)CH(2)CH(2)PPh(2))](+) complex (abbreviated [Cr(CO)(4)(dppp)](+)) in dichloromethane was investigated by CW EPR spectroscopy. Room-temperature UV irradiation results in the rapid transformation of [Cr...

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Detalles Bibliográficos
Autores principales:	Luckham, Stephen L. J., Folli, Andrea, Platts, James A., Richards, Emma, Murphy, Damien M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2019
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7009024/ https://www.ncbi.nlm.nih.gov/pubmed/32055085 http://dx.doi.org/10.1021/acs.organomet.9b00226

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