Catalytic Asymmetric C–H Arylation of (η(6)-Arene)Chromium Complexes: Facile Access to Planar-Chiral Phosphines

[Image: see text] A catalytic asymmetric direct C–H arylation of (η(6)-arene)chromium complexes to obtain planar-chiral compounds is reported. The use of the hemilabile ligand H(8)-BINAP(O) is key to providing high enantioselectivity in this transformation. We show that this methodology opens the do...

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Detalles Bibliográficos
Autores principales: Batuecas, María, Luo, Junfei, Gergelitsová, Ivana, Krämer, Katrina, Whitaker, Daniel, Vitorica-Yrezabal, Iñigo J., Larrosa, Igor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7011738/
https://www.ncbi.nlm.nih.gov/pubmed/32064145
http://dx.doi.org/10.1021/acscatal.9b00918

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7011738/
https://www.ncbi.nlm.nih.gov/pubmed/32064145
http://dx.doi.org/10.1021/acscatal.9b00918

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