Enantioselective synthesis of P-chiral tertiary phosphine oxides with an ethynyl group via Cu(i)-catalyzed azide–alkyne cycloaddition

We report the highly enantioselective synthesis of P-chiral tertiary phosphine oxides featuring an ethynyl group via Cu(i)-catalyzed azide–alkyne cycloaddition. Newly developed chiral pyridinebisoxazolines (PYBOX) bearing a bulky C4 shielding group play an important role in achieving excellent enant...

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Detalles Bibliográficos
Autores principales: Zhu, Ren-Yi, Chen, Long, Hu, Xiao-Si, Zhou, Feng, Zhou, Jian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7012078/
https://www.ncbi.nlm.nih.gov/pubmed/32110361
http://dx.doi.org/10.1039/c9sc04938j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7012078/
https://www.ncbi.nlm.nih.gov/pubmed/32110361
http://dx.doi.org/10.1039/c9sc04938j

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