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A transition-metal-free & diazo-free styrene cyclopropanation

An operationally simple and broadly applicable novel cyclopropanation of styrenes using gem-diiodomethyl carbonyl reagents has been developed. Visible-light triggered the photoinduced generation of iodomethyl carbonyl radicals, able to cyclopropanate a wide array of styrenes with excellent chemosele...

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Detalles Bibliográficos
Autores principales: Herraiz, Ana G., Suero, Marcos G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7017872/
https://www.ncbi.nlm.nih.gov/pubmed/32110302
http://dx.doi.org/10.1039/c9sc02749a