Cargando…
Highly selective hydrogenation of amides catalysed by a molybdenum pincer complex: scope and mechanism
A series of molybdenum pincer complexes has been shown for the first time to be active in the catalytic hydrogenation of amides. Among the tested catalysts, Mo-1a proved to be particularly well suited for the selective C–N hydrogenolysis of N-methylated formanilides. Notably, high chemoselectivity w...
Autores principales: | Leischner, Thomas, Artús Suarez, Lluis, Spannenberg, Anke, Junge, Kathrin, Nova, Ainara, Beller, Matthias |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7020655/ https://www.ncbi.nlm.nih.gov/pubmed/32110342 http://dx.doi.org/10.1039/c9sc03453f |
Ejemplares similares
-
Low-Valent Molybdenum PNP Pincer Complexes as Catalysts
for the Semihydrogenation of Alkynes
por: Both, Niklas F., et al.
Publicado: (2022) -
Efficient and selective hydrogenation of amides to alcohols and amines using a well-defined manganese–PNN pincer complex
por: Papa, Veronica, et al.
Publicado: (2017) -
HCOOH disproportionation to MeOH promoted by molybdenum PNP complexes
por: Alberico, Elisabetta, et al.
Publicado: (2021) -
Correction: HCOOH disproportionation to MeOH promoted by molybdenum PNP complexes
por: Alberico, Elisabetta, et al.
Publicado: (2021) -
Rational selection of co-catalysts for the deaminative hydrogenation of amides
por: Artús Suàrez, Lluís, et al.
Publicado: (2020)