Highly Sensitive Graphene/Polydimethylsiloxane Composite Films near the Threshold Concentration with Biaxial Stretching

Uniformly dispersed graphene effectively improves the strain-sensing capability of the composite film under a low graphene load in nanocomposites prepared with polydimethylsiloxane (PDMS) and graphene (GNP) monolayer powder. The threshold concentration of graphene was determined by loading nanocomposites at different temperatures. For different concentrations, when using traditional uniaxial stretching, the rate of resistance change of films near the threshold concentration is five times higher than the rate of films with a high concentration. Compared with traditional uniaxial stretching, the biaxial stretching we introduced can effectively improve the sensitivity of the film by an order of magnitude. The change in the resistance of the film near the threshold concentration is due to the change of the tunnel length and the cross-section of the tunnel, whereas the high concentration of the film is due to the change of the conductive path inside the film. Biaxial stretching has different effects on films with different concentrations, but the final effect of increasing sensitivity is the same. This study provides guidance for improving the strain-sensing sensitivity of GNP/PDMS composite films and the application of biaxial tension in detecting human motions.