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The Generation of the Oxidant Agent of a Mononuclear Nonheme Fe(II) Biomimetic Complex by Oxidative Decarboxylation. A DFT Investigation

The oxidative decarboxylation of the iron(II) α-hydroxy acid (mandelic acid) complex model, biomimetic of Rieske dioxygenase, has been investigated at the density functional level. The explored mechanism sheds light on the role of the α-hydroxyl group on the dioxygen activation. The potential energy...

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Detalles Bibliográficos
Autores principales:	Parise, Angela, Muraca, Maria Costanza, Russo, Nino, Toscano, Marirosa, Marino, Tiziana
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2020
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7024176/ https://www.ncbi.nlm.nih.gov/pubmed/31947511 http://dx.doi.org/10.3390/molecules25020328

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