Tunable Aryl Imidazolium Recyclable Ionic Liquid with Dual Brønsted–Lewis Acid as Green Catalyst for Friedel–Crafts Acylation and Thioesterification

Unique tunable aryl imidazolium ionic liquids successfully catalyzed Friedel–Crafts acylation and thioesterification in sealed tubes. These reactions can form a C−C bond and a C−S bond with high atom economy. Ionic liquids exhibited high activity and catalyzed essential reactions with good to excell...

Descripción completa

Detalles Bibliográficos
Autores principales: Lin, Yi-Jyun, Wu, Yao-Peng, Thul, Mayur, Hung, Ming-Wei, Chou, Shih-Huan, Chen, Wen-Tin, Lin, Wesley, Lin, Michelle, Reddy, Daggula Mallikarjuna, Wu, Hsin-Ru, Ho, Wen-Yueh, Luo, Shun-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7024267/
https://www.ncbi.nlm.nih.gov/pubmed/31952217
http://dx.doi.org/10.3390/molecules25020352
Descripción
Sumario:Unique tunable aryl imidazolium ionic liquids successfully catalyzed Friedel–Crafts acylation and thioesterification in sealed tubes. These reactions can form a C−C bond and a C−S bond with high atom economy. Ionic liquids exhibited high activity and catalyzed essential reactions with good to excellent yields while retaining their catalytic activities for recycling.