Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles

Unusual reactivity of nitroalkanes, involving formation of aci-forms (nitronic acids or nitronates) and their subsequent interaction with carbon-based nucleophiles, is surveyed in this review.

Detalles Bibliográficos
Autores principales: Aksenov, Nicolai A., Aksenov, Alexander V., Ovcharov, Sergei N., Aksenov, Dmitrii A., Rubin, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2020
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7026128/
https://www.ncbi.nlm.nih.gov/pubmed/32117896
http://dx.doi.org/10.3389/fchem.2020.00077
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author Aksenov, Nicolai A.
Aksenov, Alexander V.
Ovcharov, Sergei N.
Aksenov, Dmitrii A.
Rubin, Michael
author_facet Aksenov, Nicolai A.
Aksenov, Alexander V.
Ovcharov, Sergei N.
Aksenov, Dmitrii A.
Rubin, Michael
author_sort Aksenov, Nicolai A.
collection PubMed
description Unusual reactivity of nitroalkanes, involving formation of aci-forms (nitronic acids or nitronates) and their subsequent interaction with carbon-based nucleophiles, is surveyed in this review.
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spelling pubmed-70261282020-02-28 Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles Aksenov, Nicolai A. Aksenov, Alexander V. Ovcharov, Sergei N. Aksenov, Dmitrii A. Rubin, Michael Front Chem Chemistry Unusual reactivity of nitroalkanes, involving formation of aci-forms (nitronic acids or nitronates) and their subsequent interaction with carbon-based nucleophiles, is surveyed in this review. Frontiers Media S.A. 2020-02-11 /pmc/articles/PMC7026128/ /pubmed/32117896 http://dx.doi.org/10.3389/fchem.2020.00077 Text en Copyright © 2020 Aksenov, Aksenov, Ovcharov, Aksenov and Rubin. http://creativecommons.org/licenses/by/4.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Aksenov, Nicolai A.
Aksenov, Alexander V.
Ovcharov, Sergei N.
Aksenov, Dmitrii A.
Rubin, Michael
Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles
title Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles
title_full Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles
title_fullStr Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles
title_full_unstemmed Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles
title_short Electrophilically Activated Nitroalkanes in Reactions With Carbon Based Nucleophiles
title_sort electrophilically activated nitroalkanes in reactions with carbon based nucleophiles
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7026128/
https://www.ncbi.nlm.nih.gov/pubmed/32117896
http://dx.doi.org/10.3389/fchem.2020.00077
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