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Unexpected Isomerization of Hexa‐tert‐butyl‐octaphosphane
Octaphosphane {cyclo‐(P(4) tBu(3))}(2) (1) undergoes an unexpected isomerization reaction to the constitutional isomer 2,2′,2′′,2′′′,3,3′‐hexa‐tert‐butyl‐bicyclo[3.3.0]octaphosphane (2) in the presence of Lewis acidic metal salts. The mechanism of this reaction is discussed and elucidated with DFT c...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7027762/ https://www.ncbi.nlm.nih.gov/pubmed/31758612 http://dx.doi.org/10.1002/chem.201904531 |