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Ge=B π‐Bonding: Synthesis and Reversible [2+2] Cycloaddition of Germaborenes
Phosphine‐stabilized germaborenes featuring an unprecedented Ge=B double bond with short B⋅⋅⋅Ge contacts of 1.886(2) (4) and 1.895(3) Å (5) were synthesized starting from an intramolecular germylene–phosphine Lewis pair (1). After oxidative addition of boron trihalides BX(3) (X=Cl, Br), the addition...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7028040/ https://www.ncbi.nlm.nih.gov/pubmed/31804742 http://dx.doi.org/10.1002/anie.201914608 |