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Ge=B π‐Bonding: Synthesis and Reversible [2+2] Cycloaddition of Germaborenes

Phosphine‐stabilized germaborenes featuring an unprecedented Ge=B double bond with short B⋅⋅⋅Ge contacts of 1.886(2) (4) and 1.895(3) Å (5) were synthesized starting from an intramolecular germylene–phosphine Lewis pair (1). After oxidative addition of boron trihalides BX(3) (X=Cl, Br), the addition...

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Detalles Bibliográficos
Autores principales:	Raiser, Dominik, Sindlinger, Christian P., Schubert, Hartmut, Wesemann, Lars
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7028040/ https://www.ncbi.nlm.nih.gov/pubmed/31804742 http://dx.doi.org/10.1002/anie.201914608

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