Crystal Engineering with Multipoint Halogen Bonding: Double Two‐Point Donors and Acceptors at Work

The combination of singly or doubly bidentate halogen‐bond donors with double bidentate acceptors was investigated as a supramolecular synthon in crystal engineering. The crystal topologies obtained feature novel halogen‐bonding motifs like double two‐point recognition and infinite chains or network...

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Autores principales: Bulfield, David, Engelage, Elric, Mancheski, Lucas, Stoesser, Julian, Huber, Stefan M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7028063/
https://www.ncbi.nlm.nih.gov/pubmed/31638284
http://dx.doi.org/10.1002/chem.201904322
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author Bulfield, David
Engelage, Elric
Mancheski, Lucas
Stoesser, Julian
Huber, Stefan M.
author_facet Bulfield, David
Engelage, Elric
Mancheski, Lucas
Stoesser, Julian
Huber, Stefan M.
author_sort Bulfield, David
collection PubMed
description The combination of singly or doubly bidentate halogen‐bond donors with double bidentate acceptors was investigated as a supramolecular synthon in crystal engineering. The crystal topologies obtained feature novel halogen‐bonding motifs like double two‐point recognition and infinite chains or networks based on two‐point interactions. Induced conformational changes in the double bidentate halogen‐bond donors could be exploited to obtain different 1D and 2D networks. All solid‐state studies were accompanied by DFT calculations to predict and rationalize the outcome.
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spelling pubmed-70280632020-02-25 Crystal Engineering with Multipoint Halogen Bonding: Double Two‐Point Donors and Acceptors at Work Bulfield, David Engelage, Elric Mancheski, Lucas Stoesser, Julian Huber, Stefan M. Chemistry Full Papers The combination of singly or doubly bidentate halogen‐bond donors with double bidentate acceptors was investigated as a supramolecular synthon in crystal engineering. The crystal topologies obtained feature novel halogen‐bonding motifs like double two‐point recognition and infinite chains or networks based on two‐point interactions. Induced conformational changes in the double bidentate halogen‐bond donors could be exploited to obtain different 1D and 2D networks. All solid‐state studies were accompanied by DFT calculations to predict and rationalize the outcome. John Wiley and Sons Inc. 2020-02-03 2020-02-03 /pmc/articles/PMC7028063/ /pubmed/31638284 http://dx.doi.org/10.1002/chem.201904322 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Full Papers
Bulfield, David
Engelage, Elric
Mancheski, Lucas
Stoesser, Julian
Huber, Stefan M.
Crystal Engineering with Multipoint Halogen Bonding: Double Two‐Point Donors and Acceptors at Work
title Crystal Engineering with Multipoint Halogen Bonding: Double Two‐Point Donors and Acceptors at Work
title_full Crystal Engineering with Multipoint Halogen Bonding: Double Two‐Point Donors and Acceptors at Work
title_fullStr Crystal Engineering with Multipoint Halogen Bonding: Double Two‐Point Donors and Acceptors at Work
title_full_unstemmed Crystal Engineering with Multipoint Halogen Bonding: Double Two‐Point Donors and Acceptors at Work
title_short Crystal Engineering with Multipoint Halogen Bonding: Double Two‐Point Donors and Acceptors at Work
title_sort crystal engineering with multipoint halogen bonding: double two‐point donors and acceptors at work
topic Full Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7028063/
https://www.ncbi.nlm.nih.gov/pubmed/31638284
http://dx.doi.org/10.1002/chem.201904322
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