Ligand Substitution of Ru(II)–Alkylidenes to Ru(bpy)(3) (2+): Sequential Olefin Metathesis/Photoredox Catalysis

Ruthenium(II) alkylidene complexes such as the Grubbs’ 1st and 2nd generation catalysts undergo a ligand substitution with 2,2′‐bipyridine, which readily leads to the common photoredox catalyst Ru(bpy)(3) (2+). The application of this catalyst transformation in sequential olefin metathesis/photoredo...

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Detalles Bibliográficos
Autores principales: Gallhof, Malte, Kell, Lukas, Brasholz, Malte
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7028069/
https://www.ncbi.nlm.nih.gov/pubmed/31851394
http://dx.doi.org/10.1002/chem.201905694
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author Gallhof, Malte
Kell, Lukas
Brasholz, Malte
author_facet Gallhof, Malte
Kell, Lukas
Brasholz, Malte
author_sort Gallhof, Malte
collection PubMed
description Ruthenium(II) alkylidene complexes such as the Grubbs’ 1st and 2nd generation catalysts undergo a ligand substitution with 2,2′‐bipyridine, which readily leads to the common photoredox catalyst Ru(bpy)(3) (2+). The application of this catalyst transformation in sequential olefin metathesis/photoredox catalysis is demonstrated by way of ring‐closing metathesis (RCM)/photoredox ATRA reactions.
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spelling pubmed-70280692020-02-25 Ligand Substitution of Ru(II)–Alkylidenes to Ru(bpy)(3) (2+): Sequential Olefin Metathesis/Photoredox Catalysis Gallhof, Malte Kell, Lukas Brasholz, Malte Chemistry Communications Ruthenium(II) alkylidene complexes such as the Grubbs’ 1st and 2nd generation catalysts undergo a ligand substitution with 2,2′‐bipyridine, which readily leads to the common photoredox catalyst Ru(bpy)(3) (2+). The application of this catalyst transformation in sequential olefin metathesis/photoredox catalysis is demonstrated by way of ring‐closing metathesis (RCM)/photoredox ATRA reactions. John Wiley and Sons Inc. 2020-01-23 2020-02-06 /pmc/articles/PMC7028069/ /pubmed/31851394 http://dx.doi.org/10.1002/chem.201905694 Text en © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Gallhof, Malte
Kell, Lukas
Brasholz, Malte
Ligand Substitution of Ru(II)–Alkylidenes to Ru(bpy)(3) (2+): Sequential Olefin Metathesis/Photoredox Catalysis
title Ligand Substitution of Ru(II)–Alkylidenes to Ru(bpy)(3) (2+): Sequential Olefin Metathesis/Photoredox Catalysis
title_full Ligand Substitution of Ru(II)–Alkylidenes to Ru(bpy)(3) (2+): Sequential Olefin Metathesis/Photoredox Catalysis
title_fullStr Ligand Substitution of Ru(II)–Alkylidenes to Ru(bpy)(3) (2+): Sequential Olefin Metathesis/Photoredox Catalysis
title_full_unstemmed Ligand Substitution of Ru(II)–Alkylidenes to Ru(bpy)(3) (2+): Sequential Olefin Metathesis/Photoredox Catalysis
title_short Ligand Substitution of Ru(II)–Alkylidenes to Ru(bpy)(3) (2+): Sequential Olefin Metathesis/Photoredox Catalysis
title_sort ligand substitution of ru(ii)–alkylidenes to ru(bpy)(3) (2+): sequential olefin metathesis/photoredox catalysis
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7028069/
https://www.ncbi.nlm.nih.gov/pubmed/31851394
http://dx.doi.org/10.1002/chem.201905694
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AT brasholzmalte ligandsubstitutionofruiialkylidenestorubpy32sequentialolefinmetathesisphotoredoxcatalysis

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